1.1 Importance of Chemistry
- Chemistry is the study of matter, its properties, and transformations.
- Plays a vital role in medicine, agriculture, industry, and environmental science.
1.2 Nature of Matter
- Matter: Anything that occupies space and has mass.
- States of matter: Solid, liquid, gas
- Composed of atoms and molecules.
1.3 Properties of Matter and their Measurement
- Physical properties: Can be observed without changing composition (e.g., density, color, melting point).
- Chemical properties: Involve change in composition (e.g., flammability, reactivity).
- Measurements: Must be precise and accurate; expressed in SI units.
1.4 Uncertainty in Measurement
- All measurements have uncertainty.
- Significant figures: Indicate precision.
- Example: 12.34 → 4 significant figures
- Error analysis helps improve reliability of results.
1.5 Laws of Chemical Combinations
- Law of Conservation of Mass: Mass of reactants = mass of products.
- Law of Definite Proportions: A compound always contains elements in fixed proportion by mass.
- Law of Multiple Proportions: Elements can combine in more than one way to form different compounds with small whole-number ratios.
1.6 Dalton’s Atomic Theory
- Matter is made of indivisible atoms.
- Atoms of same element are identical; different elements have different atoms.
- Compounds are formed by combination of atoms in simple ratios.
- Chemical reactions involve rearrangement of atoms.
1.7 Atomic and Molecular Masses
- Atomic mass: Average mass of an element’s atom relative to 12C isotope.
- Molecular mass: Sum of atomic masses in a molecule.
- Units: amu (atomic mass unit)
1.8 Mole Concept and Molar Masses
- Mole: Amount of substance containing 6.022×1023 particles (Avogadro’s number).
- Molar mass: Mass of 1 mole of a substance = molecular mass in grams.
1.9 Percentage Composition
- % Composition of an element in a compound:
%element=Molar mass of compoundMass of element×100
1.10 Stoichiometry and Stoichiometric Calculations
- Stoichiometry: Relationship between reactants and products in a chemical reaction.
- Calculations involve:
- Mole-to-mole ratios
- Mass-to-mass conversions
- Limiting reagent determination