Q1.
The root mean square (rms) speed of a gas molecule is given by:
A) m3kT
B) m2kT
C) 2mkT
D) mkT
Q2.
The pressure of an ideal gas is due to:
A) Intermolecular attraction
B) Collisions of molecules with walls
C) Gravitational force on molecules
D) Vibrations of molecules
Q3.
The average kinetic energy of a gas molecule is proportional to:
A) Pressure
B) Temperature
C) Volume
D) Mass
Q4.
For 1 mole of an ideal gas, internal energy depends on:
A) Temperature only
B) Pressure only
C) Volume only
D) Both P and V
Q5.
A gas contains molecules of mass m and rms speed v. The total kinetic energy of N molecules is:
A) 21Nmv2
B) 23Nmv2
C) 21mv2
D) 23kT
Q6.
Pressure of 1 mole of ideal gas at temperature T and volume V:
A) VRT
B) 3V2RT
C) 2VRT
D) 2V3RT
Q7.
Most probable speed of molecules in ideal gas:
A) m2kT
B) m3kT
C) mkT
D) m5kT
Q8.
Degrees of freedom of a diatomic molecule at room temperature:
A) 3
B) 5
C) 6
D) 2
Q9.
Average translational kinetic energy per molecule is:
A) 21kT
B) 23kT
C) 25kT
D) 3kT
Q10.
A gas molecule has mass m and average kinetic energy E. The rms speed is:
A) m2E
B) m3E
C) mE
D) 2mE
Q11.
Internal energy of monoatomic ideal gas per mole:
A) 23RT
B) 25RT
C) 27RT
D) 2RT
Q12.
Ratio of specific heats for monoatomic ideal gas (γ=Cp/Cv):
A) 5/3
B) 7/5
C) 3/2
D) 4/3
Q13.
The root mean square speed of oxygen molecule at 27°C is approximately 480 m/s. If temperature doubles, rms speed becomes:
A) 960 m/s
B) 680 m/s
C) 480 m/s
D) 240 m/s
Q14.
The gas exerts pressure on the wall:
A) Only when molecules move in x-direction
B) Due to collisions in all directions
C) Only when velocity is maximum
D) Only near the wall
Q15.
If the number of molecules in a container is doubled at same temperature:
A) rms speed doubles
B) Pressure doubles
C) Volume doubles
D) Internal energy halves
Q16.
Degrees of freedom for nonlinear triatomic molecule:
A) 3
B) 5
C) 6
D) 9
Q17.
Mean free path is:
A) Distance travelled before collision
B) Average distance between collisions
C) Speed × time
D) Twice the molecular radius
Q18.
Time between successive collisions of a gas molecule is:
A) Mean free path ÷ rms speed
B) rms speed ÷ mean free path
C) 2 × mean free path ÷ rms speed
D) Half of rms speed × mean free path
Q19.
Boltzmann constant k relates:
A) Gas constant to Avogadro’s number
B) Pressure and volume
C) Temperature and volume
D) Energy and mass
Q20.
Fraction of molecules moving with speed between v and v+dv follows:
A) Maxwell-Boltzmann distribution
B) Bernoulli distribution
C) Gaussian distribution
D) Fermi-Dirac distribution
Q21.
For a monoatomic gas, if temperature is halved:
A) rms speed halves
B) rms speed decreases by √2
C) rms speed decreases by 1/4
D) rms speed remains same
Q22.
Kinetic theory assumes molecules:
A) Have negligible volume, elastic collisions
B) Attract each other strongly
C) Move in circles
D) Always at rest
Q23.
If the pressure and volume are doubled, temperature:
A) Doubles
B) Remains same
C) Quadruples
D) Halves
Q24.
Average translational kinetic energy per mole for a gas:
A) 23kT
B) 23RT
C) 25RT
D) 2RT
Q25.
Internal energy of a diatomic gas at room temperature:
A) 23RT
B) 25RT
C) 3RT
D) 7/2RT
Answer
| Question No. | Answer |
|---|---|
| 1 | A |
| 2 | B |
| 3 | B |
| 4 | A |
| 5 | B |
| 6 | A |
| 7 | A |
| 8 | B |
| 9 | B |
| 10 | A |
| 11 | A |
| 12 | A |
| 13 | B |
| 14 | B |
| 15 | B |
| 16 | D |
| 17 | B |
| 18 | A |
| 19 | A |
| 20 | A |
| 21 | B |
| 22 | A |
| 23 | A |
| 24 | B |
| 25 | B |
Solution
KINETIC THEORY OF GASES – DETAILED SOLUTIONS
Q1. RMS speed of a gas molecule
vrms=m3kT
This is the standard formula.
Answer: A
Q2. Source of pressure in an ideal gas
Pressure arises due to collisions of molecules with the walls.
Answer: B
Q3. Average kinetic energy proportionality
Eavg=23kT
Depends only on temperature.
Answer: B
Q4. Internal energy of 1 mole of ideal gas
Depends only on temperature, not on pressure or volume:U=23RT(monoatomic)
Answer: A
Q5. Total kinetic energy of N molecules
Etotal=21mvrms2×Nfor each molecule?
Actually, for RMS speed vrms:Etotal=21mNvrms2
Answer: B
Q6. Pressure of 1 mole of ideal gas
PV=RT⟹P=VRT
Answer: A
Q7. Most probable speed vp
vp=m2kT
Answer: A
Q8. Degrees of freedom of a diatomic molecule at room temp
- Translational: 3
- Rotational: 2
- Vibrational modes negligible at room temp
⇒ Total f=5
Answer: B
Q9. Average translational kinetic energy per molecule
⟨Etrans⟩=23kT
Answer: B
Q10. RMS speed from average kinetic energy
E=21mvrms2⟹vrms=m2E
Answer: A
Q11. Internal energy per mole (monoatomic)
U=23RT
Answer: A
Q12. Ratio of specific heats for monoatomic gas
γ=CvCp=3/2R5/2R=5/3
Answer: A
Q13. RMS speed at doubled temperature
vrms∝T⟹vnew=4802≈680m/s
Answer: B
Q14. Pressure on wall due to molecules
- Collisions occur in all directions
- Contribution along x, y, z combined
Answer: B
Q15. Doubling number of molecules at same T
- RMS speed depends on temperature → unchanged
- Pressure P=VNkT → doubles
Answer: B
Q16. Degrees of freedom of nonlinear triatomic molecule
- Translational: 3
- Rotational: 3
- Vibrational: neglected at room temp
Total f=6
Answer: D
Q17. Mean free path
- Average distance travelled between successive collisions
Answer: B
Q18. Time between successive collisions
t=vrmsmean free path
Answer: A
Q19. Boltzmann constant
k=NAR
Relates gas constant to Avogadro number
Answer: A
Q20. Distribution of molecular speeds
- Follows Maxwell-Boltzmann distribution
Answer: A
Q21. Temperature halved
vrms∝T⟹vnew=vold/2
Answer: B
Q22. Assumptions of kinetic theory
- Molecules have negligible volume
- Collisions are elastic
Answer: A
Q23. Pressure & volume doubled
PV=nRT⟹T doubles
Answer: A
Q24. Average translational kinetic energy per mole
Eavg=23RT
Answer: B
Q25. Internal energy of diatomic gas (room temp)
- Translational: 3/2 RT
- Rotational: RT (2 × 1/2 RT)
- Total: 5/2 RT
Answer: B